Annealing Basics – Part 1

By cizentrysite on November 2, 2017
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Contributed By Mike Glasman.

Part of the journey towards being “Best in Class” as a club is providing understandable and pertinent technical information to help make informed decisions on what is needed to be safe and provide an edge to excel. This month we begin with the first of three articles about the art and science of annealing rifle brass. After reading these articles, you should have a good idea of what happens to rifle brass when it’s fired, what annealing is, and how it’s done.

Let’s begin with a question: Is it possible to make brass last longer and produce tighter groups? It may sound too good to be true — after all, we usually expect to give up something to get something else. However, when case necks are annealed, neck splitting is far less likely to occur; and it has been shown that group sizes shrink. With the expense of buying brass and the effort to prep match brass, getting more life out of the brass should appeal to those that have a limited quantity available to them.

Next Question: What happens to a brass case when it’s fired and re -sized? We know it grows in diameter and length, because it must be re-sized and trimmed. Other unseen things occur due to being stretched and forced back to original size by the re-sizing die. The brass becomes work hardened, loses some ductility, becomes a bit stronger in yield strength, moves closer to its ultimate tensile strength, and hardness increases slightly. These unseen changes increase the likelihood of neck cracking and case head separation. There can also be inconsistent neck tension when seating bullets. Further, harder brass does not seal as well against the inside of the chamber when the round is fired. Fortunately, ductility in the neck of the case can be recovered and consistent neck tension can be achieved by annealing. Before going further, keep in mind that annealing is not a cure-all for splitting or separations in the straight wall section of the case. Proper annealing only affects the neck and a bit of the shoulder of the brass. Do NOT anneal the case below the shoulder, because the brass is designed and processed to have a minimum strength below the shoulder.

Now, let’s define the terms above in bold italics and tie them together to form an in-depth understanding of how the brass case performs and what annealing does.

Work Hardening: An increase in the strength of the brass case due to firing and re-sizing. This occurs due to complex changes at the atomic level within the brass. All you need to know is that every time you fire a round it becomes work hardened, becomes a bit stronger, and loses some ductility.

Ductility: The ability of the brass to experience repeated cycles of firing and being re-sized without cracking. When a round is fired, the pressure from inside the case and tension from extraction, expands and stretches the case. When resizing, you compress it back to a size less than what it was when ejected, so it will fit in the chamber and reliably extract next time you use the case. Key point is that each time the case is fired and re-sized, it gets a bit stronger and a bit less ductile — closer to failure. Fortunately brass has the right combination of strength and ductility to allow multiple cycles of use without a significant loss of ductility.

• Yield Strength: The strength of the brass associated with the amount of stress imposed on it right up to the point where the brass will spring back to its original size. Beyond that point, the brass needs to be re-sized and trimmed back to specification dimensions. As the brass is work-hardened, the yield strength and hardness of the brass goes up a bit every time — and approaches the ultimate tensile strength at which point failure is
experienced.

Tensile Strength: (Ultimate Tensile Strength) The amount of stress the brass can take right before necks crack and caseheads separate. The tensile strength does not change appreciably, and when yield strength (which increases due to work hardening) equals tensile strength, failure occurs.

Hardness: The ability of the brass to resist indentation — or ability to seal against the surface of the rifle chamber. A good seal puts more pressure behind the bullet and less gas in your face and eyes. Cases aren’t as blackened and come out a bit cleaner, too. As strength is increased, hardness increases as well.

Neck Tension: The “grip” exerted on the projectile by the brass as measured by the difference in diameter between the case mouth and diameter of the projectile (bullet), and the ability of the brass to maintain position of that projectile during routine handling and when stripped out of the magazine and chambered during auto-loading modes. The ability of the brass to maintain that grip on the bullet depends on the strength of the brass in contact with the projectile. So, even if you have the nominal 0.002″ difference between the diameter of the bullet and case mouth opening, you don’t get proper neck tension if the brass yields excessively (is too weak) to maintain a needed level of tension to keep the bullet in place. So, when the round is stripped out of the magazine, the bullet will edge forward out of the case when the round is rapidly accelerated into the chamber, and slams to a sudden stop in front of an in-battery bolt; the bullet will move forward right at the instant it is chambered. This may create some accuracy issues on the target face, or worse. Bottom line is excessive annealing times and temperatures may produce neck tensions to be too low to use for magazine-fed ammo. And if annealed beyond a certain point, it is not possible to re-use the brass for much of anything. This is where the rubber meets the road for what follows with annealing.

Annealing: For our purposes, annealing and sufficient recovery of ductility (or relaxation of residual stress in the brass) occurs when it attains 750ºF IN THE CASE NECK ABOVE THE SHOULDER with no discernable hold time – just a second or two is sufficient. This is the first of three stages of annealing, and is called Recovery. Any hotter than 750ºF or longer hold times will cause a transition to the next two stages (recrystallization and grain growth) of annealing, which is undesirable. We must stay in the recovery stage and not anneal below where the neck transitions to the shoulder. If recrystallization or grain growth occurs, or you approach 750ºF below the shoulder of the case, that case should be discarded.

You now have the basic vocabulary for understanding what happens to a brass case when it’s fired and re-sized, and what annealing can do to extend the life of rifle brass and make neck tension more consistent. In part two, we will discuss how to determine annealing temperature.

Note that this article shared by Mike Glasman was previously posted in the Oak Ridge Sportsman’s Association Rifle & Pistol Newsletter.